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姓 名： | 谭理 |
| 性 别： | 男 | |
| 职 称： | 教授（博导） | |
| 学 历： | 博士研究生 | |
| 职 务： | 院长助理 | |
| 电 话： | ||
| 专 业： | 物理化学/工业催化 | |
| 电子邮件： | tan@fzu.edu.cn | |
| 研究方向： | C1化学与原位表征 |
教育工作经历
2009-2013，太原理工大学学院， B.S.
2013-2015，日本国立富山大学，M.S. (导师：Noritatsu Tsubaki 教授)
2015-2018，日本国立富山大学，Ph.D. (导师：Noritatsu Tsubaki 教授)
2018-2023，亚洲bet57365游戏大厅，副教授，博导，旗山学者，共同建立并负责分子催化与原位表征研究所
2023-至今，亚洲bet57365游戏大厅，校聘教授
教学简介
物理化学
物理化学实验
材料物理化学
科研简介
从事工业催化反应过程中反应路线的设计、催化材料的合成及其在低碳分子催化转化所涉及的反应过程中的应用。聚焦于C1化学多相催化反应及相关催化剂体系的设计和原位表征研究，应用于合成气或CO2加氢制备油品(汽油，柴油，航空燃油)及化学品(含氧化物、低碳烯烃、芳烃)，丙烷脱氢，甲烷转化等重要低碳资源利用相关催化反应过程。主持国家自然科学基金及多项省部级重点项目，发表论文70余篇，以第一或通讯作者发表在 Nature Catalysis, Chemical Science, 化工三大刊等学术期刊。获福建省高层次B类引进人才，旗山学者等人才项目支持。
社会兼职
《Resources Chemicals and Materials》责任编辑，《燃料化学学报》学术编辑，《Journal of Energy Chemistry》青年编委，《低碳化学与化工》青年编委，《结构化学》青年编委
科研项目
主持：
国家自然科学基金联合基金项目子课题（2023-2026，120/300万元）
科技部重点研发计划子课题（2022-2026，45/1200万元）
国家自然科学基金面上项目（2022-2025，78万元）
福建省自然科学基金青创项目（2020-2023，8万元）已结题
学院”旗山学者“海外项目（2020-2023，30万元）已结题
国家自然科学基金青年基金（2020-2022，31.2万元）已结题
省部共建煤炭高效利用与绿色化工国家重点实验室省部级重点项目（2019-2021，5万元）已结题
煤转化国家重点实验室省部级重点项目（2019-2020，12万元）已结题
部分代表性论文
2024
62. Pengfei Zhu*, Heyang Cao, Hua Yang, Mengrong Geng, Shuang Qin, Li Tan*, Xinhua Gao, Chuanyi Wang, One-pot synthesis of Ni(Ⅱ)-doped UiO-66-NH2 for enhanced photocatalytic CO2 reduction to CO with efficient charge transfer, Applied Surface Science, 2024, 652, 159348.
61. Wenjie Cui, Yudong Xia, Peipei Zhang, Yajie Fu, Xue Ye, Jie Li, Li Tan*, The pivotal role of bromine in FeMnKBr/YNa catalyst for CO2 hydrogenation to light olefins, iScience, 2024, 27(5), 109621.
60. Yuyan Gan, Qian Lv, Yanru Li, Lizhi Wu, Yu Tang, Yuanxing Fang, Pengfei Zhu*, Li Tan *, Photocatalytic oxidation of methane to methanol over zinc titanate supported silver catalysts, Journal of Rare Earths, 2024. DOI: 10.1016/j.jre.2024.01.009
59. Yuan Fang#, Fan Wang#, Yang Chen#, Qian Lv, Kun Jiang, Hua Yang, Huibo Zhao, Peng Wang, Yuyan Gan, Lizhi Wu, Yu Tang, Xinhua Gao, Li Tan*, Realizing methanol synthesis from CO and water via the synergistic effect of Cu0 /Cu+ over Cu/ZrO2 catalyst, Journal of Energy Chemistry, 2024,93: 126-134.
58. Kaiyang Xu, Yu Chen, Hua Yang, Yuyan Gan, Lizhi Wu, Li Tan, Yihu Dai, Yu Tang*, Partial Hydrogenation of Anisole to Cyclohexanone in Water Medium Catalyzed by Atomically Dispersed Pd Anchored in the Micropores of Zeolite, Applied Catalysis B: Environmental, 2024, 341, 123244.
57. Kun Jiang, Huibo Zhao, Yang Chen, Baozhen Li, Zhang Zhang, Fenghai Cao, Lizhi Wu, Yu Tang, Tiesen Li*, Li Tan*, Tuning Interfaces between Cu and Oxide via Atomic Layer Deposition Method for CO2 Hydrogenation to Methanol, Catalysis Science & Technology, 2024, 14: 261- 266.
56. Zemin An, Nan Ma, Yuanjie Xu, Hua Yan, Huibo Zha, Lizhi W, Li Tan, Chao Zou, Fanchun Men, Bin Zhang, Xiuyun Wan, Yu Tang*, Shape dependency of CO2 hydrogenation on ceria supported singly dispersed Ru catalysts, Journal of Catalysis, 2024, 429, 115245.
2023
55. Yuhan Wang, Yue Liu, Li Tan*, Xiahui Lin, Yuanxing Fang*, Xue Feng Lu, Yidong Hou, Guigang Zhang, Sibo Wang*, Confining ultrafine Pt nanoparticles on In2O3 nanotubes for enhanced selective methanol production by CO2 hydrogenation, Journal of Materials Chemistry A, 2023, 11, 26804-26811.
54. Ying Zhang, Xiaofang Wang, Huihui Deng, Qin Sun, Baozhen Li, Wenchun Zheng, Zhuangzhuang Ren, Xiangqing Fang, Li Tan, Yu Tang, Lizhi Wu*, Synergistic mechanism of isolated Fe3+ and highly dispersed Ptδ+ over zeolite for boosting propane dehydrogenation, AIChE Journal, 2023, 69 (12), e18249.
53. Peng Wang, Huafei Liao, Meng Yang, Lizhi Wu, Yu Tang, Li Tan*, Constructing rich-Zn Pt1Zn1 alloy over the BEA zeolite as a selective catalyst for propane dehydrogenation, Fuel, 2023, 354, 129421.
52. Hua Yang, Zemin An, Yuanjie Xu, Lizhi Wu*, Li Tan*, Yu Tang*, Oscillatory behavior of Ni/TiO2 catalyst during partial oxidation of methane: Understanding the role of strong metal-support interaction, Molecular Catalysis, 2023, 547, 113374.
51. Yuanjie Xu, Zemin An, Xin Y, Jikang Yao, Qian Lv, Hua Yang, Zhengang Lv, Huichuang Guo, Qike Jian, Wei Liu, Lizhi Wu, Li Tan, Yihu Dai, Yu Tang*, Enhanced catalytic stability and structural evolution of Rh-BN interface in dry reforming of methane under intensified CO2 partial pressure, Journal of Catalysis, 2023, 427, 115094.
50. Jie Yao#, Fenghai Cao#, Yu Han#, Yang Wan*, Li Tan*, Jian Sun*, Guohui Yang*, Lei Shi*, C1 Chemistry: The Stories of Research and Applications from Toyama, Resources Chemicals and Materials, 2023, 3(1), 62-92.
49. Hua Yang, Zhang Zhang, Yongsheng He, Peng Wang, Zhuangzhuang Ren, Lizhi Wu*, Yu Tang*, and Li Tan*, Study of Ni Catalysts with Different Al2O3 Supports in the Partial Oxidation of Methane Reaction, Industrial & Engineering Chemistry Research, 2023, 62(31), 12120–12132.
48. Shuya Zhang, Xiaochen Liu, Hongqiao Lin, Rong Chen, Yu Chen, Yuanjie Xu, Kaiyang Xu, Huibo Zhao, Li Tan, Lizhi Wu, Yu Tang*, Unveiling the in-situ formation of single-atomically dispersed Pd-Fe bimetallic catalytic sites during anisole hydrodeoxygenation, Molecular Catalysis, 2023, 547, 113401.47.Yanru Li, Lingyi Zhuang, Li Tan*, Qiao Chen, Yuanxing Fang*, Rational Design of Liquid Metal Organic Frameworks for the Enhanced CO2 Absorption and Their Photocatalytic Reduction, ChemCatChem,2023, 15(15), e202300386.
46. Yongsheng He, Huihui Deng, Ying Zhang, Xiaofang Wang, Wenchun Zheng, Zhuangzhuang Ren, Li Tan, Yu Tang, Lizhi Wu*, Boosting propane dehydrogenation over Sn stabilizing dispersed Ptδ+ confined in Silicalite-1 at low temperature, Fuel, 2023, 352, 129044.
45. Haoquan Guo, Xinyu Lu, Yue Yang, Jinhe Wei, Lizhi Wu, Li Tan, Yu Tang*, Xiaoli Gu*, Harvesting alkyl phenols from lignin monomers via selective hydrodeoxygenation under ambient pressure on Pd/α-MoC catalysts, Molecular Catalysis, 2023, 540, 113041.
44. Nana Gong, Tao Zhang, Minghui Tan, Liyan Wang, Jiaqian Yang, Li Tan, Guohui Yang, Peng Wu, Yingquan Wu*, Yisheng Tan*, Realizing and Revealing Complex Isobutyl Alcohol Production over a Simple Cu–ZrO2 Catalyst, ACS Catal. 2023, 13, 6, 3563–3574
43. Peng Wang, Meng Yang, Huafei Lia, Kaiyang X, Xupeng Zong, Zailai Xie, Huibo Zhao, Yuanjie Xu, Hua Yan, Yuyan Gan, Yuan Fan, Lizhi Wu, Yu Tang*, Li Tan*, Restructured zeolites anchoring singly dispersed bimetallic platinum and zinc catalysts for propane dehydrogenation, Cell Reports Physical Science, 2023, 4(3), 101311.
42. Peng Wang, Huafei Liao, Hua Yang, Qian Lv, Yanru Li, Lizhi Wu, Yu Tang, Zailai Xie, Li Tan*, Constructing PtCe cluster catalysts by regulating metal-support interaction via Al in zeolite for propane dehydrogenation, Chemical Engineering Science, 2023, 269, 118450.
41. Yuyan Gan, Qian Lv, Yanru Li, Hua Yang, Kaiyang Xu, Lizhi Wu, Yu Tang, Li Tan*, Acidity Regulation for Improved Activity of Mo/HZSM-5 Catalyst in Methane Dehydroaromatization, Chemical Engineering Science,2023, 266, 118289.
40. Yuntao Xu, Yan fei Cao, Li Tan*, Qiao Chen, Yuanxing Fang*, The development of cobalt phosphide co-catalysts on BiVO4 photoanodes to improve H2O2 production, Journal of Colloid and Interface Science, 2023, 633, 323-332.
39. Caixia Zhu, Kaizhuang Xu, Yuan Fang, Qian Lv, Kun Jiang, Huibo Zhao, Yang Chen, Peng Wang, Hua Yang, Lizhi Wu, Yu Tang, Li Tan*, Synergetic effect of Ce/Zr for ethanol synthesis from syngas over Rh-based catalyst, Fuel, 2023, 334, 126770.
38. Lizhi Wu, Jinhe Wei, Ying Zhang, Yongsheng He, Xiaofang Wang, Haoquan Guo, Yu Tang, Li Tan*, The selective hydrodeoxygenation of guaiacol to cyclohexanol over cobalt-modified TS-1 catalysts, Microporous and Mesoporous Materials, 2023, 348, 112347.
37. Li Tan*, Yanru Li, Qian Lv, Yuyan Gan, Yuan Fang, Yu Tang, Lizhi Wu*, Yuanxing Fang*, Development of soluble UiO-66 to improve photocatalytic CO2 reduction, Catalysis Today, 2023, 410, 282–288.
2022
36. 续开壮, 吕倩, 曹逢海, 李艳茹, 吴立志*, 谭理*, Ce改性的Rh-UiO-66-Zr催化剂对合成气制乙醇的影响, 燃料化学学报，2022，50(12):1591-1600
35. Hongqiao Lin, Ping Sun, Yuanjie Xu, Xupeng Zong, Hua Yang, Xiaochen Liu, Huibo Zhao, Li Tan, Lizhi Wu, Yu Tang* Enhanced selective cleavage of aryl C-O bond by atomically dispersed Pt on α-MoC for hydrodeoxygenation of anisole, Molecular Catalysis 531 (2022) 112652
34. Huibo Zhao, Ruofan Yu, Sicong Ma, Kaizhuang Xu, Yang Chen, Kun Jiang, Yuan Fang, Caixia Zhu, Xiaochen Liu, Yu Tang, Lizhi Wu, Yingquan Wu, Qike Jiang, Peng He, Zhipan Liu*， Li Tan*, The role of Cu1–O3 species in single-atom Cu/ZrO2 catalyst for CO2 hydrogenation, Nature Catalysis, 2022, 5, 818–831
33. Xiaochen Liu, Shuya Zhang, Huibo Zhao, Hongqiao Lin, Kaiyang Xu, Yuanjie Xu, Li Tan, Lizhi Wu， Yu Tang*， In-situ studies on the synergistic effect of Pd-Mo bimetallic catalyst for anisole hydrodeoxygenation, Molecular Catalysis 530 (2022) 112591
32. Zhuangzhuang Ren, Yongsheng He, Meng Yang, Huihui Deng, Ying Zhang, Hua Yang, Zhimou Tang, Li Tan, Yu Tang， Lizhi Wu*, The investigation into the different Co species over Silicalite-1 via modulating heat-treatment atmosphere for propane dehydrogenation, Molecular Catalysis 530 (2022) 112580
31. Lizhi Wu*, Zhiyuan Fu, Jinhe Wei, Huihui Deng, Ying Zhang, Yu Tang, Li Tan*, The investigation into the dehydroaromatization of ethane over cobalt-modified ZSM-5 catalyst， Microporous and Mesoporous Materials 343 (2022) 112159
30. Hua Yang, Ruofan Yu, Yuan Fang, Jikang Yao, Yuyan Gan, Jian Chen, Hongtao Deng, Xinhua Gao, Xupeng Zong, Jinming Wang, Lizhi Wu, Li Tan*, Yu Tang*, Singly Dispersed Ir1Ti3 Bimetallic Site for Partial Oxidation of Methane at High Temperature, Applied Surface Science 599 (2022) 153863
29. Peng Wang, Jikang Yao, Qike Jiang, Xinhua Gao, Dong Lin, Hua Yang, Li Wu, Yu Tang*, Li Tan*, Stabilizing the Isolated Pt Sites on PtGa/Al2O3 Catalyst via Silica Coating Layers for Propane Dehydrogenation at Low Temperature, Applied Catalysis B: Environmental, 300(2022) 120731.
2021
28. Lizhi Wu*, Zhuangzhuang Ren, Yongsheng He, Meng Yang, Yunkai Yu, Yueming Liu, Li Tan, Yu Tang*, Atomically Dispersed Co 2+ Sites Incorporated into a Silicalite-1 Zeolite Framework as a High-Performance and Coking-Resistant Catalyst for Propane Nonoxidative Dehydrogenation to Propylene, ACS Appl. Mater. Interfaces 2021, 13, 41, 48934–48948
27. Yan Chen, Li Tan, Hui Zhang, Xue Zhang, Qiyuan Chen, Haojie Jiang, Fengjuan Ge, Shuai Wei, Xinhua Gao & Peng Wang*, Metal-free in situ carbon-nanotube-modified mesoporous graphitic carbon nitride nanocomposite with enhanced visible light photocatalytic performance, Research on Chemical Intermediates, 2021. 47, 3349–3362
26. Lizhi Wu*, Zhiyuan Fu, Zhuangzhuang Ren, Jinhe Wei, Xinhua Gao, Li Tan, Yu Tang, Enhanced Catalytic Performance of Fe‐containing HZSM‐5 for Ethane Non‐Oxidative Dehydrogenation via Hydrothermal Post‐Treatment, ChemCatChem, 2021,13,4019– 4028
2020
25. Li Tan, Fan Wang, Peipei Zhang, Yuichi Suzuki, Yingquan Wu, Jiangang Chen, Guohui Yang* and Noritatsu Tsubaki*, Design of the core-shell catalyst: an effective strategy for suppressing side reactions in syngas to light olefins direct selective conversion, Chemical Science (cover paper), 2020, 11, 4097-4105.
24. Peng Lu, Qingjun Chen, Guohui Yang, Li Tan, Xiaobo Feng, Jie Yao, Yoshiharu Yoneyama, Noritatsu Tsubaki*, Space-Confined-Self-Regulation Mechanism from Capsule Catalyst to Realize an Ethanol Direct Synthesis Strategy, ACS Catalysis, 2020, 10, 1366-1374.
2019
23. Li Tan*, Peipei Zhang, Yuichi Suzuki, Hangjie Li, Lisheng Guo, Yoshiharu Yoneyama, Jiangang Chen, Xiaobo Peng*, and Noritatsu Tsubaki*, Bifunctional capsule catalyst of Al2O3@Cu with strengthened dehydration reaction field for direct synthesis of dimethyl ether from syngas, Industrial&Engineering Chemistry Research, 2019, 58, 22905-22911.
22. Luan Nguyen, Shiran Zhang, Li Tan*, Yu Tang, Jingyue Liu, Franklin (Feng) Tao*, Ir1Znn Bimetallic Site for Efficient Production of Hydrogen from Methanol, ACS Sustainable Chemistry&Engineering, 2019, 7, 18793-18800.
21. Wang Yang, Li Tan, Minghui Tan, Peipei Zhang, Yuan Fang, Yoshiharu Yoneyama, Guohui Yang, Noritatsu Tsubaki, Rationally Designing Bifunctional Catalysts as an Efficient Strategy to Boost CO2 Hydrogenation Producing Value-Added Aromatics, ACS Catalysis, 2019, 9, 895-901.
20. Caixia Zhu, Yuan Fang, Zaiqi Luo, Cheng Zhang, Xipin Zhang, Jie Li*, Jiangang Chen, Li Tan*, Direct dimethyl ether synthesis over mesoporous Cu-Al2O3 catalyst via CO hydrogenation, Research on Chemical Intermediates, 2019, 45, 5863-5876.
19. Li Tan*, Xiaoyu Guo, Xinhua Gao, Noritatsu Tsubaki*, Designing a Mesoporous Zeolite Catalyst for Products Optimizing in n-Decane Hydrocraking, Catalysts, 2019, 9,766
18. Yingquan Wu, Li Tan*, Tao Zhang, Hongjuan Xie, Guohui Yang, Noritatsu Tsubaki, Jiangang Chen, Effect of Preparation Method on ZrO2-Based Catalysts Performance for Isobutanol Synthesis from Syngas, Catalysts, 2019, 9,752
17. Li Tan, Peipei Zhang, Yu Cui, Yuichi Suzuki, Hangjie Li, Lisheng Guo, Guohui Yang*, Noritatsu Tsubaki*, Direct CO2 hydrogenation to light olefins by suppressing CO by-product formation, Fuel Processing Technology, 2019, 196, 106174
16. Li Tan*, Yingquan Wu*, Tao Zhang, Hongjuan Xie, Jiangang Chen, Effect of precipitation temperature on the performance of K-CuLaZrO2 catalyst for isobutanol synthesis from syngas, Journal of Fuel Chemistry and Technology, 2019, 47, 1096-1103
Before joining FZU in Oct. 2018
15. Jie Li#, Yingluo He#, Li Tan#, Peipei Zhang#, Xiaobo Peng*, Oruganti Anjaneyulu, Guohui Yang, Hideki Abe, Ye Wang*, Noritatsu Tsubaki*, Integrated tunable synthesis of liquid fuels via Fischer-Tropsch technology, Nature Catalysis, 2018, 1, 787–793.
14. Peipei Zhang, Guohui Yang, Li Tan, Peipei Ai, Ruiqin Yang, Noritatsu Tsubaki, Direct synthesis of liquefied petroleum gas from syngas over H-ZSM-5 enwrapped Pd-based zeolite capsule catalyst, Catalysis Today, 2018, 303,77-85.
13. Peipei Zhang#, Li Tan#, Guohui Yang*, Noritarsu Tsubaki*, One-pass selective conversion of syngas to para-xylene, Chemical Science (cover paper), 2017, 8,7941-7946.
12. Li Tan, Oyunkhand Erdenebaatar, Guoguo Liu, Noriyuki Yamane, Peipei Ai, Akihisa Otani, Yoshiharu Yoneyama*, Guohui Yang*, Noritatsu Tsubaki*, Catalytic cracking of 4-(1-naphthylmethyl)bibenzyl in sub- and supercritical water, Fuel Processing Technology, 2017, 160, 34-38.
11. Noriyuki Yamane, Yang Wang, Jie Li, Yingluo He, Peipei Zhang, Letrunghieu Nguyen, Li Tan, Peipei Ai, Xiaobo Peng, Ye Wang, Guohui Yang and Noritatsu Tsubaki, Building premium secondary reaction field with a miniaturized capsule catalyst to realize efficient synthesis of a liquid fuel directly from syngas, Catalysis Science&Technology, 2017,7,1996-2000.
10. Shaopeng Tian, Li Tan, Yingquan Wu, Yongli Kou, Hongjuan Xie, Noritatsu Tsubaki, Yisheng Tan, The role of different state ZnO over non-stoichiometric Zn–Cr spinel catalysts for isobutanol synthesis from syngas, Applied Catalysis A: General, 2017, 536, 57-66.
9. Ronggang Fan, Masahiro Kyodo, Li Tan, Xiaobo Peng, Guohui Yang, Yoshiharu Yoneyama, Ruiqin Yang, Qingde Zhang, Noritatsu Tsubaki, Preparation and application of Cu/ZnO catalyst by urea hydrolysis method for low temperature methanol synthesis from syngas, Fuel Processing Technology, 2017, 167, 69-77.
8. Qinhong Wei, Guohui Yang, Xinhua Gao, Li Tan, Peipei Ai, Peipei Zhang, Peng Lu, Yoshiharu Yoneyama, Noritatsu Tsubaki, A facile ethanol fuel synthesis from dimethyl ether and syngas over tandem combination of Cu-doped HZSM35 with Cu-Zn-Al catalyst, Chemical Engineering Journal, 2017, 316, 832-841.
7. Peng Lu, Chuang Xing, Hangjie Li, XikunGai, Qinhong Wei, Li Tan, Chengxue Lu, Wenzhong Shen, Ruiqin Yang, Noritatsu Tsubaki, An in-situ synthesis of low-cost mesostructured nickel nanoparticles embedded carbon/silica composite via a solid–liquid grinding route and its application for the carbon dioxide reforming of methane, International Journal of Hydrogen Energy,2016, 41, 10680-10687.
6. Chuang Xing, Guohui Yang, Peng Lu, Wenzhong Shen, Xikun Gai, Li Tan, Jianwei Mao, Tiejun Wang, Ruiqin Yang, Noritatsu Tsubaki, A hierarchically spherical Co-based zeolite catalyst with aggregated nanorods structure for improved Fischer–Tropsch synthesis reaction activity and isoparaffin selectivity, Microporous and Mesoporous Materials, 2016, 233, 62-69
5. Li Tan, Guohui Yang, Yoshiharu Yoneyama, Yongli Kou, Yisheng Tan*, Tharapong Vitidsant*, Noritatsu Tsubaki*, Iso-butanol direct synthesis from syngas over the alkali metals modified Cr/ZnO catalysts, Applied Catalysis A: General 505 (2015) 141–149
4. Chuang Xing, Jian Sun, Guohui Yang, Wenzhong Shen, Li Tan, Pengfei Zhu, Qinhong Wei, Jie Li, Masahiro Kyodo, Ruiqin Yang, Yoshiharu Yoneyama, Noritatsu Tsubaki*, Tunable isoparaffin and olefin synthesis in Fischer–Tropsch synthesis achieved by composite catalyst Fuel Processing Technology 136 (2015) 68–72
3. Chuang Xing, Guohui Yang, Mingbo Wu, Ruiqin Yang, Li Tan, Pengfei Zhu, Qinhong Wei, JieLi, Jianwei Mao, Yoshiharu Yoneyam, Noritatsu Tsubaki*, Hierarchical zeolite Y supported cobalt bifunctional catalyst for facilely tuning the product distribution of Fischer–Tropsch synthesis, Fuel, 148 (2015) 48–57
2. Ying-quan WU, Hong-juan XIE, Yong-li KOU, Li Tan, Yi-zhuo HAN, Yi-sheng TAN*, Effect of calcination temperature on performance of K-Cu/Zn/La/ZrO2 for isobutanol synthesis, J Fuel Chem Technol, 2013, 41(7), 868-874
1. Jianfeng Chen, Yurui Zhang, Li Tan, Yi Zhang*, A Simple Method for Preparing the Highly Dispersed Supported Co3O4 on Silica Support, Ind. Eng. Chem. Res. 2011, 50, 7, 4212–4215
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