姓 名：杨凯

                   职 称：副研究员/博士生导师

                   学 历：博士

                   电子邮件：kyang@fzu.edu.cn

                   研究方向：有机硼化学

                   招生专业：有机化学

热忱欢迎对有机硼化学、有机合成和不对称催化感兴趣的同学报考硕士、博士研究生，欢迎报考我们团队老师（请点击查看更多信息:欢迎访问宋秋玲教授课题组）

教育工作经历

2020.11～至今学院，亚洲bet57365游戏大厅，副研究员

2018.09～2020.10学院，亚洲bet57365游戏大厅，博士后

2013.09～2018.06华侨大学，化工学院，博士

2009.09～2013.06南华大学，药学院，学士

教学简介

本科有机化学、有机化学实验

科研简介

致力于发展高效、高选择性和普适的方法合成手性有机硼化合物，并探索这类化合物在医药、催化以及材料化学等领域的应用，以及探索硼原子的引入对反应和手性化合物性质的影响。将有机硼化学与手性化学有机结合起来，是我们未来重点关注与研究的方向。

社会兼职

科研项目

(1) 国家自然科学基金面上项目（2023-2026）

(2) 国家自然科学基金青年基金（2021-2023）

(3) 福建省自然科学基金青创项目（2022-2025）

代表性论文

21. Zhang, X.; Su, W.; Guo,H.; Fang, P.; Yang, K.*; Song, Q.* N-Heterocycle-Editing to Access Fused-BN-Heterocycles via Ring-Opening/C-H Borylation/Reductive C-B Bond Formation”, Angew. Chem. Int. Ed. 2024, DOI: 10.1002/anie.202318613.

20.Wang, H.; Qiao, B.;Zhu, J.; Guo, H.; Zhang, Z.;Yang, K.*; Li, S.-J.; Lan, Y.*; Song, Q.* Enantio- and Regioselective [2 + 2 + 2] Cycloaddition of BN-Diynes for Construction of C-B Axial Chirality.Chem 2024,10, 317-329.

19.Xu, J.; Qiu, W.; Zhang, X.; Wu, Z.; Zhang, Z.;Yang, K.*; Song, Q.* Palladium‐Catalyzed Atroposelective Kinetic C−H Olefination and Allylation for the Synthesis of C−B Axial Chirality.Angew. Chem. Int. Ed.2023,62, e202313388.

18. Yang, K.# Mao,Y.#Zhang, Z.# Xu, J.; Wang, H.; He,Y.; Yu, P.*; Song, Q.* Construction of C-B axial chirality via dynamic kinetic asymmetric cross-coupling mediated by tetracoordinate boron,Nat. Commun. 2023, 14, 4438.

17. Wang, C.; Zhou, L.; Qiu, J.;Yang, K.*; Song, Q.* Rh-Catalyzed diastereoselective addition of arylboronic acids to α-keto N-tert-butanesulfinyl aldimines: synthesis of α-amino ketones.Org. Chem. Front.2022,9, 1016-1022.

16. Xu, H.; Ye, M.;Yang, K.*; Song, Q.* Regioselective Cross-Coupling of Isatogens with Boronic Acids to Construct 2,2-Disubstituted Indolin-3-one Derivatives.Org. Lett.2021,23, 7776-7780.

15.Yang, K.; Mao, Y.; Xu. J.; He, Y.; Li, W.; Song, Q.* Construction of axially chiral arylborons via atroposelective miyaura borylation.J. Am. Chem. Soc.2021,143, 10048-10053.

14.Yang, K.; Song, Q.* Tetracoordinate boron intermediates enable unconventional transformations.Acc. Chem. Res.2021,54, 2298-2312.

13.Yang, K.; Zhang, F.; Fang, T.; Li, C.; Li, W.; Song, Q.* Passerini-type reaction of boronic acids enables α-hydroxyketones synthesis.Nat. Commun.2021,12, 441.

12.Yang, K.; Hu, X., Li, W.; Qiu, J.; Feng, Q.; Wang, S.; Zhang, G.; Kuang, Z.; Yu, P.*; Song, Q.*Transition-metal-free double insertive coupling of isocyanides with arylboronic acids enabled diarylmethanamines.Cell Rep. Phys. Sci.2020,1, 100268.

11.Yang, K.; Kuang, Z.; Song, Q.*Radical-induced 1,2-boron shift, enabling 1,3-difunctionalization of allylboronic esters.Chem,2020,6, 330-331.

10.Yang, K.; Lou, Y.; Wang, C.; Qi, L.-W.; Fang, T.; Zhang, F.; Xu, H.; Zhou, L.; Li, W.; Zhang, G.; Yu, P.*; Song, Q.*Chiral brønsted acid from chiral phosphoric acid boron complex and water: asymmetric reduction of indoles.Angew. Chem. Int. Ed.2020,59, 3294-3299.

9.Yang, K.; Zhang, F.; Fang, T.; Zhang, G.; Song, Q.*Stereospecific 1,4-metallate shift enables stereoconvergent synthesis of ketoximes.Angew. Chem. Int. Ed.2019,58, 13421–13426.

8.Yang, K.; Zhang, G.; Song, Q.*Four-coordinate triarylborane synthesis via cascade B–Cl/C–B cross-metathesis and C–H bond borylation.Chem. Sci.2018,9, 7666-7672.

7.Yang, K.; Song, Q.* Transition-metal-free regioselective synthesis of alkylboronates from arylacetylenes and vinyl arenes.Green Chem.2016,18, 932-936.

6.Yang, K.; Ke, M.; Lin, Y.; Song, Q.* Sulfonamide formation from sodium sulfinates and amines or ammonia under metal-free conditions at ambient temperature.Green Chem.2015,17, 1395-1399.

5.Yang, K.; Song, Q.* Pd-Catalyzed Regioselective Arylboration of Vinylarenes.Org. Lett.2016,18, 5460−5463.

4.Yang, K.; Song, Q.*. Fe-Catalyzed Double Cross-Dehydrogenative Coupling of 1,3-Dicarbonyl Compounds and ArylmethanesOrg. Lett.2015,17, 548-551.

3.Yang, K.;Zhou, F.; Kuang, Z.; Gao, G.; Driver, T. G.; Song, Q.* Diborane-Mediated Deoxygenation ofo‑Nitrostyrenes To Form Indoles.Org. Lett.2016,18, 4088-4091.

2.Yang, K.; Song, Q.* Palladium-Catalyzed Arylboration of Bicyclic Alkenes.J. Org. Chem.2016,81, 1000-1005.

1.Yang, K.; Song, Q.* Styryl ether formation from benzyl alcohols under transition-metal-free basic DMSO conditions.Org. Biomol. Chem.2015,13, 2267-2272.

其他